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Author(s): K. W. Muir, D. G. Morris, K. S. Ryder, A. Varvoglis

The title disulfonyl-stabilized pyridinium ylide, C5H5N+C-(SO2C6H5)(2) or C18H15NO4S2, contains a near planar NCS2 core. The structure suggests that the formal negative charge of the ylide C atom is delocalized to the S atoms rather than the N atom. Structural features of pyridinium ylides are briefly discussed.

Full version: Available here

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ISBN: 0108-2701
Publication Year: 2003
Periodical: Acta Crystallographica Section C-Crystal Structure Communications
Periodical Number:
Volume: 59
Pages: O376-O377
Author Address: