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eLearning

SINAPSE experts from around Scotland have developed ten online modules designed to explain medical imaging. They are freely available and are intended for non-specialists.


Edinburgh Imaging Academy at the University of Edinburgh offers the following online programmes through a virtual learning environment:

Neuroimaging for Research MSc/Dip/Cert

Imaging MSc/Dip/Cert

PET-MR Principles & Applications Cert

Applied Medical Image Analysis Cert

Online Short Courses

Acetonitrile hydration versus molybdenum oxidation at the sulfur-rich bimetallic site {(Mo2Cp2)-Cp-III(mu-SMe)(3)}(+). Crystal structure of the mu-eta(1):eta(1)-amidato complex [Mo2Cp2(mu-MeCONH)(mu-SMe)(3)]

Author(s): P. Schollhammer, M. Le Henanf, C. L. R. Le Floch, F. Y. Petillon, J. Talarmin, K. W. Muir

Abstract:
The paramagnetic mu -amidato species [Mo2Cp2(mu -MeCONH)(mu -SMe)(3)]BF4 2a(+) (Cp=eta -C5H5) is formed exclusively when the compound [Mo2Cp2(MeCN)(2)(mu -SMe)(3)]BF4 1a in powder form is kept in air, whereas the same starting complex in solution gives a mixture of the mu -amidato species and the mu -oxo complex [Mo2Cp2(mu -O)(mu -SMe)(3)]BF4 3. The oxo complex is formed quantitatively on warming [Mo2Cp2(mu -Cl)(mu -SMe)(3)]BF4 in water. The reduction of 2a(+) by NaBH4 in CH3CN affords the molecular product [Mo2Cp2(mu -MeCONH)(mu -SMe)(3)] 2a which has been characterised by X-ray analysis.

Full version: Available here

Click the link to go to an external website with the full version of the paper


ISBN: 1472-7773
Publication Year: 2001
Periodical: Journal of the Chemical Society-Dalton Transactions
Periodical Number: 10
Volume:
Pages: 1573-1577
Author Address: