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Synthetic studies on the pederin family of antitumour agents. Syntheses of mycalamide B, theopederin D and pederin

Author(s): P. Kocienski, R. Narquizian, P. Raubo, C. Smith, L. J. Farrugia, K. Muir, F. T. Boyle

A general modular approach to the members of the pederin family of antitumour agents is exemplified by syntheses of mycalamide B and theopederin D as well as a formal synthesis of pederin. All three compounds are prepared from 6-lithio-2,3-dimethyl-4-phenylselenomethyl-3,4-dihydro-2H-pyran and 2-(3-chloropropyl)-3,3-dimethyl-3,4-dihydro-2H-pyran-4-one.

Full version: Available here

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ISBN: 1470-4358
Publication Year: 2000
Periodical: Journal of the Chemical Society-Perkin Transactions 1
Periodical Number: 15
Pages: 2357-2384
Author Address: