2nd Scottish Ultrasound Annual Scientific Meeting Feb 28, 2020 10:00 AM - 05:00 PM — Collins Building, University of Strathclyde
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8th Annual Scottish Radiotherapy Research Forum Mar 12, 2020 10:00 AM - 04:30 PM — Stirling Court Hotel, University of Stirling
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eLearning

SINAPSE experts from around Scotland have developed ten online modules designed to explain medical imaging. They are freely available and are intended for non-specialists.


Edinburgh Imaging Academy at the University of Edinburgh offers the following online programmes through a virtual learning environment:

Neuroimaging for Research MSc/Dip/Cert

Imaging MSc/Dip/Cert

PET-MR Principles & Applications Cert

Applied Medical Image Analysis Cert

Online Short Courses

Unexpected coupling of Cp and two RNC ligands at a {Mo-2(mu-SMe)(3)} nucleus

Author(s): N. Cabon, E. Paugam, F. Y. Petillon, P. Schollhammer, J. Talarmin, K. W. Muir

Abstract:
Reaction of the bis-isonitrile complex [Mo-2-Cp-2(mu-SMe)(3)(t-BuNC)(2)](BF4) (1) with n-BuLi (in hexane) produced the dealkylated derivative [Mo2Cp2(mu-SMe)(3)(t-BuNC)(CN)] (2) in quantitative yield. However, upon treatment with either NaOH (suspension) or (Me4N)OH (in MeOH), 1 was converted into a mixture of 2 and the mu-alkylidyne species [Mo2Cp(mu-SMe)(3){mu-(eta(5)-C5H4)(t-BuN)-CN(t-Bu)C}] (3), in which a deprotonated Cp and both isonitrile ligands of 1 are now linked by new carbon-carbon and carbon-nitrogen bonds.

Full version: Available here

Click the link to go to an external website with the full version of the paper


ISBN: 0276-7333
Publication Year: 2003
Periodical: Organometallics
Periodical Number: 21
Volume: 22
Pages: 4178-4180
Author Address: