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Formation of octapod MnO nanoparticles with enhanced magnetic properties through kinetically-controlled thermal decomposition of polynuclear manganese complexes

Author(s): Fraser J. Douglas, Donald A. MacLaren, Floriana Tuna, William M. Holmes, Catherine C. Berry, Mark Murrie

Polynuclear manganese complexes are used as precursors for the synthesis of manganese oxide nanoparticles (MnO NPs). Altering the thermal decomposition conditions can shift the nanoparticle product from spherical, thermodynamically-driven NPs to unusual, kinetically-controlled octapod structures. The resulting increased surface area profoundly alters the NP's surface-dependent magnetism and may have applications in nanomedicine.

Full version: Available here

Click the link to go to an external website with the full version of the paper

ISBN: 2040-3364
Publication Year: 2014
Periodical: Nanoscale
Periodical Number: 1
Volume: 6
Pages: 172-176
Author Address: