Formation of C-C, C-N, and C-O links between isonitrile, cyclopentadienyl, and hydroxide ligands bound to molybdenum(III): Syntheses and crystal structures of mu-aminocarbyne and mu-amino-oxycarbene dimolybdenum complexes

Reaction of the bis- isonitrile complex [Mo2Cp2(mu-SMe)(3)(xylNC)(2)](BF4) (2b) with NaOH (suspension) under reflux in tetrahydrofuran produced, in quantitative yields, the A-alkylidyne species [Mo2Cp(mu-SMe) (3){mu-(5-C5H4)(xylN)CN(xyl)C}] (4), in which a deprotonated Cp …more

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