Author(s)

K. W. Muir, D. G. Morris, C. O. W. Chii

ISBN

0108-2701

Publication year

2004

Periodical

Acta Crystallographica Section C-Crystal Structure Communications

Periodical Number

Volume

60

Pages

M60-M62

Author Address

Full version

In the title compound, hexa-mu-chloro-dichlorotetrakis(Ntrimethylammonio-p-toluenesulfonamidate -kappa(2)N,O)tetramer- cury(II), [Hg{Me3N(+)N(-)SO2C6H4CH3-p}Cl-2](4) or [Hg4Cl8(C10H16N2O2S)(4)], four nearly linear and parallel Cl-Hg-Cl units associate through pairwise Hg…Cl interactions of 3.1-3.2Angstrom. Each Hg atom is also coordinated through N and O atoms to a ylide molecule. The available structural data indicate that coordination of a sulfonyl-stabilized nitrogen ylide to a metal atom (Hg or Ag) has no detectable effect on its geometry.