The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (+/-)-erythro- and (+/-)-threo-9,10-difluorostearic acids

Author(s)

M. Tavasli, D. O'Hagan, C. Pearson, M. C. Petty

ISBN

1359-7345

Publication year

2002

Periodical

Chemical Communications

Periodical Number

Volume

Pages

1226-1227

Author Address

Full version

October 27, 2022

(+/-)-Erythro-and(+/-)-threo-9,10-difluorostearic acids which differ only by a stereogenic interconversion of a single C-F bond, have significantly different conformational stabilities.